【作者】 余小红； 张汉辉； 孙瑞卿； 曹彦宁； 王振；

【Author】 YU Xiao-hong, ZHANG Han-hui , SUN Rui-qing, CAO Yan-ning, WANG Zhen Department of Chemistry, Fuzhou University, Fuzhou 350002, China

【机构】 福州大学化学系；

【摘要】 文章在水热条件下,合成了一种新颖的具有孔洞的三维的含铋的草酸化合物(C3N2H5)2 [Bi2(C2O4)4(H2O)2]·2H2O。X-ray单晶衍射表明该化合物属于单斜晶系,具有孔洞的三维广延结构。为了研究其结构与性能的关系,对其进行了FTIR,UV-Vis,Raman和荧光光谱的研究,并对其进行了归属。应用Material studio的CASTEP软件对其进行能带计算。更多还原

【Abstract】 A novel bismuth oxalate, (C3 N2 H5) 2 [Bi2 (C2 O4) 4 ( H2 O) 2 ] · 2 H2 O, was synthesized under hydrothermal condition. Single crystal X-ray structure analyses reveal that the compound belongs to monoclinic systems, and has a 3D open-framework structure with channels. In order to reveal the structure-property relationships, the compound was characterized by FTIR, UV-Vis DRS, and fluorescence spectrum. The energy bonds were calculated using CASTEP program of material studio.更多还原