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新型树枝形表面活性剂在纳米银相转移领域的应用

Application of Novel Dendrimer Surfactants to Transfer of Silver Nanoparticles in an Organic Solvent

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【作者】 高楠张豪周晓海张高勇

【Author】 Gao Nan, Hao Zhang, Zhou Xiaohai*, Zhang Gaoyong Colloid and Interface Science Lab. College of Chemistry and Molecular Science, Wuhan University, Wuhan,China,430072

【机构】 武汉大学化学与分子科学学院胶体与界面科学实验室

【Abstract】 Novel 0 and 1 generation multi-headed dendrimer surfactants, based on dedocylamine, were synthesized. The molecular structures were characterized by IR, UV-vis, NMR and FAB-MS. They have good solubility in water and high surface activity. The 12-0G modified silver nanoparticles could be transferred from water to organic phase with high efficiency. The transference is the concentration of novel dendrimer surfactant dependent. In the solvent toluene, these silver nanoparticals are very stable and do not grow or aggregate over a period of several days and the solid product is antioxidation even exposed to air at high temperature. The diameter of silver nanoparticles is about 7nm.

【关键词】 树枝形表面活性剂纳米银相转移
  • 【会议录名称】 中国化学会第二十五届学术年会论文摘要集(下册)
  • 【会议名称】中国化学会第二十五届学术年会
  • 【会议时间】2006-07
  • 【会议地点】中国吉林长春
  • 【分类号】O614.122
  • 【主办单位】中国化学会
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