节点文献
三甲基硅基苯乙炔与羰基化合物的光化反应
Photoinduced reactions of Quinones with phenyltrimethylsilylacetylene
【Author】 Lei Wang, Zhe Li, Jian-Hua Xu School of Chemistry & Chemical Engineering, Nanjing University, 210093, Nanjing
【机构】 南京大学化学化工学院；
【Abstract】 Photoreactions of benzoquinone with phenyltrimethylsilylacetylene (1) resulted in desilylation and formal C≡C bond scission to give benzophenone derivatives.These reactions are suggested to proceed via acyl silane intermediates.Photoreactions of 1-acetylisatin with 1 can also be rationalized by a mechanism involving acyl silane intermediate.
- 【会议录名称】 中国化学会第二十五届学术年会论文摘要集（下册）
- 【会议名称】中国化学会第二十五届学术年会
- 【会议时间】2006-07
- 【会议地点】中国吉林长春
- 【分类号】O644.1
- 【主办单位】中国化学会