【作者】 蔡双莲； 陈云；

【Author】 Shuang-Lian Cai, Yun Chen* Department of Chemistry, Hunan University, 410082, changsha

【机构】 湖南大学化学化工学院；

【Abstract】 Metal-organic coordination polymers have been largely investigated because of their special properties in catalysis,absorption,optics,electronics,magnetic etc. Hexamethylenetetramine (hmt) is a potentially tetradentate tetrahedral ligand. Mostly, hmt ligand gives nets with alternate metallic and organic centres. Reported herein are the synthesis, crystal structure and some relevant physicochemical studies of a new 3-D coordination polymer [Cd2Cl4(hmt)(MeOH)2] with interpenetrating diamond nets formed from Cd connectors and hmt nodes. The geometry of the supramolecular array is driven only by the hmt units.更多还原