节点文献
[(HOCH2)3CNH3]6[V10O28]的合成、晶体结构及性质研究
Synthesis, Properties and Crystal Structure of [(HOCH2)3CNH3]6[V10O28]
【Author】 *Yin-Zhuang Zhou, Hai-Ping Qiao, Dai-Di Hu Department of Chemistry, Capital Normal University, Beijing, 100037
【机构】 首都师范大学化学系;
【Abstract】 A new inorganic-organic hybrid compound [(HOCH2)3CNH3]6[V10O28] has been synthesized and characterized by IR, UV-Vis, cyclic voltammetry and X-ray diffraction. The compound is based on decavanadate cluster [V10O28]6-. The hydrogen bonding interactions and ion actions among [(HOCH2)3CNH3]+ and [V10O28]6- extend it into a three-dimensional supramolecular architecture. Photochromism of the compound show that the electron transfer takes place from [(HOCH2)3CNH3]+ to [V10O28]6- and the electrochemical property indicates that potential difference of redox peak relates to the scan rate in the H2SO4 solution of 2.0 mol/L.
- 【会议录名称】 中国化学会第二十五届学术年会论文摘要集(下册)
- 【会议名称】中国化学会第二十五届学术年会
- 【会议时间】2006-07
- 【会议地点】中国吉林长春
- 【分类号】O621.3
- 【主办单位】中国化学会