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[(HOCH23CNH3]6[V10O28]的合成、晶体结构及性质研究

Synthesis, Properties and Crystal Structure of [(HOCH23CNH3]6[V10O28]

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【作者】 周荫庄乔海平胡代娣

【Author】 *Yin-Zhuang Zhou, Hai-Ping Qiao, Dai-Di Hu Department of Chemistry, Capital Normal University, Beijing, 100037

【机构】 首都师范大学化学系

【Abstract】 A new inorganic-organic hybrid compound [(HOCH2)3CNH3]6[V10O28] has been synthesized and characterized by IR, UV-Vis, cyclic voltammetry and X-ray diffraction. The compound is based on decavanadate cluster [V10O28]6-. The hydrogen bonding interactions and ion actions among [(HOCH2)3CNH3]+ and [V10O28]6- extend it into a three-dimensional supramolecular architecture. Photochromism of the compound show that the electron transfer takes place from [(HOCH2)3CNH3]+ to [V10O28]6- and the electrochemical property indicates that potential difference of redox peak relates to the scan rate in the H2SO4 solution of 2.0 mol/L.

【关键词】 十钒酸根有机-无机盐合成晶体结构性质
  • 【会议录名称】 中国化学会第二十五届学术年会论文摘要集(下册)
  • 【会议名称】中国化学会第二十五届学术年会
  • 【会议时间】2006-07
  • 【会议地点】中国吉林长春
  • 【分类号】O621.3
  • 【主办单位】中国化学会
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