【作者】 郝洪庆； 宣为民； 黄小青； 邹方； 章慧； 陈坚固；

【Author】 Hong-Qing Hao, Wei-Min Xuan, Xiao-Qing Huang, Fang Zou, Hui Zhang*, Jian-Gu Chen Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, 361005, Xiamen

【机构】 厦门大学化学化工学院化学系；

【Abstract】 Researches revealed that bridged binuclear copper (II) complexes played an important role in catalysis, magnetics, biology and medicine.[1-5] Compound 1 and 2 represent the first examples of mixed-ligand complexes of Hpyta and also the first binuclear complexes of Hpyta. The copper (II) is in a distorted square pyramidal coordination geometry with a long axial coordination to X? [X = Cl, Br]. The 2,2’-bipy acts as a bidentate terminal ligand. The complexes 1 and 2 contain four and two crystal waters respectively.更多还原