节点文献
杂多酸[(H3dien)2(P2Mo5O23)](dien=diethylenetriamine)的水热合成及晶体结构
Hydrothermal Syntheses and Structural Characterization of [(H3dien)2(P2Mo5O23)](dien=diethylenetriamine)
【Author】 Xiao Zhang, Jing Lu, Jie-hui Yu, Ji-qing Xu* College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin, 130021, China
【机构】 吉林大学化学学院和无机合成与制备化学国家重点实验室;
【Abstract】 The crystal of [(H3dien)2(P2Mo5O23)] (dien = diethylenetriamine) consist of the heteropolyanion, (P2Mo5O23)6- and full-protonated dien. The structure is stabilized by hydrogen bonding between the nitrogen atoms of dien and the oxygen atoms of the (P2Mo5O23)6- anion. The cluster anion (P2Mo5O23)6- is built up from five MoO6 octhedra sharing four edges and one corner forming a five-member ring capped by two PO4 tetrahedra.
【基金】 国家自然科学基金支助项目(No.20333070和No.20571032)
- 【会议录名称】 中国化学会第二十五届学术年会论文摘要集(下册)
- 【会议名称】中国化学会第二十五届学术年会
- 【会议时间】2006-07
- 【会议地点】中国吉林长春
- 【分类号】O611.3
- 【主办单位】中国化学会