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配位聚合物氨基多羧酸钾的合成与晶体结构解析
Synthesis and Structure of Potassium polymer with amino-poly carboxylic acid as ligand
【作者】 张宝丽; 张元红; 张兴晶; 韩晶; 邢永恒; 牛淑云;
【Author】 Zhang Baoli, Zhang Yuanhong, Zhang Xingjing, Han Jing, Xing Yongheng* and Niu Shuyun (College College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, 116029,
【机构】 辽宁师范大学化学化工学院;
【Abstract】 The title complex [K(C14H18N2O8)·CH3OH·H2O]n was synthesized, and its structure was determined by X-ray diffraction. The crystal data shows: triclinic, space group P-1, a = 0.8759(16) nm, b = 0.9306(17) nm,c = 1.1574(10) nm, α=84.382(2)°,β = 87.471(2)°,γ=87.187(2)°, V=0.937(3)nm3, Z =2, R1 = 0.0517, WR2 = 0.1394. A view of asymmetrial unit cell of the title complex and the structure of the title complex are shown in Fig. 1 and Fig. 2, respectively.
- 【会议录名称】 中国化学会第二十五届学术年会论文摘要集(下册)
- 【会议名称】中国化学会第二十五届学术年会
- 【会议时间】2006-07
- 【会议地点】中国吉林长春
- 【分类号】O631.3
- 【主办单位】中国化学会