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新颖超分子铁配合物的合成、结构及其三阶非线性性能
Synthesis, crystal structure and third-order non-linear optical properties of a iron (Ⅲ) supramolecular compound
【Author】 Zhao-Xia Zhang, Yong Li*, Wen-Dong Song College of Science, Guangdong Ocean University, 524088, Zhanjiang
【机构】 广东海洋大学理学院；
【Abstract】 The iron (III) complex [Fe(8-HQ)3]·0.5CH3OH (8-HQ = 8-hydroxyquinoline), was synthesized by using solid state reaction. The crystal of the compound belongs to monoclinic, space group P2(1)/n, with the crystal cell parameters: a = 10.9006(4) ?, b = 13.1017(6) ?, c = 16.6690(9) ?, β = 97.582(3)o, V = 2359.79(19) ?3 , Z = 4, R1 = 0.0491, wR2 = 0.1326. The third-order nonlinear absorption coefficient and third-order nonlinear refractive index are respectively, α2 = 7.65×10-12 m/w and n 2 = -–6.5×10-17 m2/w.
【基金】 广东海洋大学博士启动基金(0512101);湛江引进人才创业项目(0509044)资助。
- 【会议录名称】 中国化学会第二十五届学术年会论文摘要集（下册）
- 【会议名称】中国化学会第二十五届学术年会
- 【会议时间】2006-07
- 【会议地点】中国吉林长春
- 【分类号】O641.4
- 【主办单位】中国化学会