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簇合物[Fe(DMF)6][Mo2(μ-S)2(S2)2]合成、结构及三阶非线性性能
Syntheses, structures and third-order nonlinear optical properties of clusters containing molybdenum[Fe(DMF)6] [Mo2(μ-S)2(S2)2]
【Author】 Zhao-Xia Zhang, Yong Li*, Wen-Dong Song College of Science, Guangdong Ocean University, 524088, Zhanjiang
【机构】 广东海洋大学理学院;
【Abstract】 The title compound [Fe(DMF)6] [Mo2(μ-S)2(S2)2] was synthesized from low-temperature solid-phase method, and its structure was determined. The complex crystallizes in the triclinic space group P-1 with a = 8.8119(18) ?, b = 9.838(2) ?, c = 11.374(2) ?, V = 899.6(3) ?3, Z = 2, R1 = 0.0592, wR2 = 0.0592. The third-order nonlinear absorption coefficient and third-order nonlinear refractive index are,respectively, α2 = 9.34×10-11 m/w and n2 = –6.7×10-17 m2/w.
【基金】 广东海洋大学博士启动基金(0512101);湛江引进人才创业项目(0509044)资助。
- 【会议录名称】 中国化学会第二十五届学术年会论文摘要集(下册)
- 【会议名称】中国化学会第二十五届学术年会
- 【会议时间】2006-07
- 【会议地点】中国吉林长春
- 【分类号】O614.811
- 【主办单位】中国化学会