【作者】 张兴晶； 张元红； 张宝丽； 韩晶； 邢永恒； 牛淑云；

【Author】 Zhang Xingjing, Zhang Yuanhong, Zhang Baoli, Han Jing, Xing Yongheng* and Niu Shuyun (College College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, 116029, )

【机构】 辽宁师范大学化学化工学院；

【Abstract】 Tris(1-pyrazolyl)borates were invented by Trofimeko, and today are well established as ligands in coordination chemistry. Scorpionates with transition metals are now found useful in a wide range of chemistry. Using tris(pyrazolyl)borate(or tetra(pyrazolyl)borate) and Cu(C4H4O4) as starting materials, two new copper complex with poly(pyrazolyl)borate were synthesized, Cu(B(pz)4)2(1) and Cu(HB(pz Me2)3)2(2). Their structure are depicted in Fig. 1 and Fig. 2, respectively.更多还原