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叠氮根桥联的一维链配合物[Co（N3）2（4,4’-dmbpy）]的合成和晶体结构
Synthesis and crystal structure of an azido-bridged 1D chain complex [Co（N3）2（4,4’-dmbpy）]
【Author】 Yu-Zhi Su , Min Xu,Wen Dong * Department of Chemistry, School of Chemical Engineering and Technology, Guangzhou University, Guangzhou,510006)
【机构】 广州大学化学化工学院；
【Abstract】 Recently , the study of 1D chain complexes of 3d metal bridged by cyano or azido group have drawn extensive attention due to their possible applications as 1D chain magnets. CN- and N3- groups exhibit an electronic exchange path mediating the interaction among spins localized on paramagnetic centers. Here a 1D chain complex [Co(N3)2(4,4’-dmbpy)] has been synthesized and structurally characterized by single crystals X-ray diffraction.
- 【会议录名称】 中国化学会第二十五届学术年会论文摘要集（上册）
- 【会议名称】中国化学会第二十五届学术年会
- 【会议时间】2006-07
- 【会议地点】中国吉林长春
- 【分类号】O641.4
- 【主办单位】中国化学会