节点文献
带TMS基团的π-共轭四、六邻联噻吩大环化合物的合成
High Yield Synthesis of Macrocyclic Compounds,Tetra[2,3-thienylene] and Hexa[2,3-thienylene] Bearing TMS Group
【Author】 Yangguang Wanga, Zhihua Wanga, Yanxiang Chengb, Dongfeng Zhaoa and Hua Wanga* a, Key Lab for Special Functional Materials, Henan University, Kaifeng, 475001, P.R.China b, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P.R.China
【机构】 河南大学特种功能材料重点实验室； 中国科学院长春应有化学研究所；
【Abstract】 The derivatives of thiophene are widely used in nonlinear optical (NLO) materials, organic semiconductor, organic thin film transistors(OTFT), organic light electric diode(OLED) and field effect transistor (FET). Here, we report the synthesis of π conjugated tetra-[2,3-thienylene] (1, ~28% yield) and hexa-[2,3-thienylene] (2, ~24% yield) from 3-bromothiophene via four moisture sensitive reaction steps.
- 【会议录名称】 中国化学会第二十五届学术年会论文摘要集（上册）
- 【会议名称】中国化学会第二十五届学术年会
- 【会议时间】2006-07
- 【会议地点】中国吉林长春
- 【分类号】O626.12
- 【主办单位】中国化学会