节点文献
光促进温和条件下烯烃与甲酸甲酯的氢甲酯化研究
Photo Promoted Methoxycarbonylation of Olefin with Methyl Formate under Ambient Conditions
【Author】 Ying-na Cui, Jing-mei Yin,* Da-bin Gao, Ying-ping Jia, Guang-yun Zhou College of Environment and Chemical Engineering, Dalian University, 116622, Dalain
【机构】 大连大学环境与化学工程学院;
【Abstract】 The photo promoted methoxycarbonylation of olefins with methyl formate catalyzed by non-precious metal complexes can be carried out under ambient conditions. The study indicates that methyl formate decomposes into CO and CH3OH first under irradiation, and then the methoxycarbonylation of olefin proceeds under the catalysis of cobalt or copper complexes. The method without involving CO gas as a direct carbon source makes the operation of methoxycarbonylation convenient and safe.
【基金】 国家自然科学基金(No.20372012);辽宁省自然科学基金(No.20032099)资助项目
- 【会议录名称】 中国化学会第二十五届学术年会论文摘要集(上册)
- 【会议名称】中国化学会第二十五届学术年会
- 【会议时间】2006-07
- 【会议地点】中国吉林长春
- 【分类号】O621.25
- 【主办单位】中国化学会