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蒜头果油合成环十五内酯新方法
New method of Synthesis of Cyclopentadecanolide by Malania Olceifera Chum oil
【Author】 LIU Xiong-Min, LI Wei-Guang, LI Piao-Ying, ZHOU Yong-Hong (Guangxi University, Nanning 53004)
【机构】 广西大学化学化工学院;
【Abstract】 Triglycerides of ω -hydroxycarboxylic acids synthesized from Malania Oleifera Chum oil via ozonization and reduction were catalytically transformed to macrocyctic lactones, this new method involved fewer steps and resulted in a 63% yield, the reactive properties ofω-hydroxycarboxylic acids were also studied. The result showed that the short chainω-hydroxycarboxylic acids were preferentially cyclized.
【基金】 教育部科学技术重点项目(204110);广西自然科学基金项目(桂科自0135013)
- 【会议录名称】 中国化学会第二十五届学术年会论文摘要集(上册)
- 【会议名称】中国化学会第二十五届学术年会
- 【会议时间】2006-07
- 【会议地点】中国吉林长春
- 【分类号】TQ235
- 【主办单位】中国化学会