节点文献
Cu(Ⅱ)模板三乙烯四胺化交联聚苯乙烯大孔树脂的合成及对Cu(Ⅱ)/Ni(Ⅱ)的分离性能
Synthesis and separation properties for Cu(Ⅱ)/Ni(Ⅱ) of crosslinked polystyrene-supported triethylenetrtramine resin using Cu(Ⅱ) as template
【Author】 Chang-Mei Sun1,2, Rong-Jun Qu2, Guo-Xiang Cheng1 1 School of Materials Science & Engineering, Tianjin University, 300072, Tianjin 2 School of Chemistry and Materials Science, Yantai Normal University, 264025, Yantai
【机构】 天津大学材料科学与工程学院; 烟台师范学院化学与材料科学学院;
【Abstract】 Firstly, the aminated resin was synthesized by the reaction of crosslinked macroporous chloromethylated polystyrene with triethylenetrtramine, and then it coordinated with Cu(II). After the cross linking reaction with epoxy chloropropane, the adsorbed Cu(II) was removed by chlorhydric acid and then the target resin— Cu(II) template triethylenetrtramine crosslinked polystyrene resin-was obtained. SEM images showed that plenty of macro pores scattered on the surface of the resin. Also, the resin could selectively adsorb Cu(II) with the coexistence of Ni(II) and selective coefficients α Cu2+/ Ni2+ was 9.06
- 【会议录名称】 中国化学会第二十五届学术年会论文摘要集(上册)
- 【会议名称】中国化学会第二十五届学术年会
- 【会议时间】2006-07
- 【会议地点】中国吉林长春
- 【分类号】TQ320;O647.3
- 【主办单位】中国化学会