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Cu/Sepiolite选择催化还原NO的性能及机理的研究

Study on the Performance and Mechanism of Cu/Sepiolite for NO Selective Catalytic Reduction

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【作者】 杨扬李丽王道

【Author】 Yang Yang﹡,Li Li,Dao Wang Environmental and Energy Engineering College, Beijing University of Technology, Beijing 100022, P.R.China

【机构】 北京工业大学环境与能源工程学院

【Abstract】 The modification conditions of sepiolite was chosen by orthogonal experiments. The catalysts for reduction of NO with CO was made of Copper Nitrate solution impregnated on modified sepiolite. The catalytic performance of Cu/sepiolite was studied under oxidizing conditions. The samples were characterized by TGA, XRD, BET and H2-TPR. The maximum conversion of NO in the presence of oxygen was observed on the Cu (5wt.%)/sepiolite which was calcinated at 400℃ . The addition of Ce and Sm to Cu/sepiolite catalysts had been found to improve the catalytic properties. Under the same experimental conditions, the catalytic activity of Cu/sepiolite was better than Cu/ZSM-5 catalyst.

【关键词】 海泡石催化剂NO选择还原
【基金】 北京市自然科学基金项目,编号8062025
  • 【会议录名称】 中国化学会第二十五届学术年会论文摘要集(上册)
  • 【会议名称】中国化学会第二十五届学术年会
  • 【会议时间】2006-07
  • 【会议地点】中国吉林长春
  • 【分类号】O643.32
  • 【主办单位】中国化学会
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