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[Et3NH]Cl/CuCl离子液体的合成及其在汽油萃取脱硫中的应用研究

Synthesis of [Et3NH]Cl/CuCl Ionic Liquids and Its Application in Desulfurization of Gasoline by Extracting

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【作者】 张志刚王娜李翔宇李雪刚刘冉赵地顺

【Author】 Zhi-gang Zhang1, Na Wang1, Xiang-yu Li2, Xue-gang Li2, Ran Liu2, Di-shun Zhao*2 1. College of Science, Hebei University of Science and Technology, 050018, Shijiazhuang Hebei 2.College of Chemistry and Pharmaceutical Engineering, Hebei University of Science and Technology, 050018, Shijiazhuang Hebei

【机构】 河北科技大学理学院河北科技大学化学与制药工程学院

【Abstract】 This ionic liquid was synthesized by mixing [Et3NH]Cl with CuCl,and the cation was characterized using 1H NMR.In the experimentas, at 60℃ ,the ratio of Ionic Liquids to Gasoline is 1:5 and no N2 protections, sulfur removal of Gasoline is the best.As an extraction absorbent,[Et3NH]Cl/CuCl ionic liquid exhibited remarkable desulfurization ability in the desulfurization of gasoline, and the cost is much lower.The effectiveness of sulfur removal may be attributed to the complexation of Cu(I) with thiophene, which shows promise as an approach for the deep desulfurization of motor fuel.

【关键词】 离子液体脱硫汽油萃取
【基金】 国家自然科学基金项目(项目编号:20576026)
  • 【会议录名称】 中国化学会第二十五届学术年会论文摘要集(上册)
  • 【会议名称】中国化学会第二十五届学术年会
  • 【会议时间】2006-07
  • 【会议地点】中国吉林长春
  • 【分类号】TE624.55
  • 【主办单位】中国化学会
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