【作者】 范素兵； 赵宁； 李军平； 魏伟； 孙予罕；

【Author】 Su-bing Fan, Ning Zhao, Jun-ping Li, Wei Wei, Yu-han Sun* State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, 030001, Taiyuan, P.R.China

【机构】 中科院山西煤炭化学研究所；

【Abstract】 A novel route for pyrrole-1-carbonate (1-MPC) synthesis from methoxycarbonylation of pyrrole by dimethyl carbonate (DMC) was proposed and the reaction parameter of the reaction was investigated in this paper. It was found that methyl pyrrole-1-carbonate could be produced with high selectivity over alkaline earth metal oxide. The optimized reaction condition was as follows: reaction temperature 200℃, reaction time 3h, molar ratio of DMC to Pyrrole was 2. The process is a green route for the synthesis of 1-MPC because it avoids toxic, expensive catalysts and solvents and also the aimed product is separated easily.更多还原