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二甲醚在Pt(110)和Pt(111)单晶电极上的电化学氧化行为(英文)

Electrooxidation of Dimethyl ether (DME) on Pt(110) and Pt(111) single crystal electrodes

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【作者】 仝玉进邵玉艳尹鸽平

【Author】 Yujin Tong, Yuyan Shao, Geping Yin (PO Box 411, Department of Applied Chemistry, Harbin Institute of Technology, Harbin 150001)

【机构】 哈尔滨工业大学应用化学系

【摘要】 <正>Recently, Dimethyl ether (DME) has attracted attention as a promising fuel in fuel cell. The electrochemical oxidation of DME on a polycrystalline electrode has been conducted recently by Shao et al. However, little work has been done on the electrochemical oxidation of DME on Pt single electrodes. Our aim is to find the different electrochemical oxidation characteristics of DME on Pt(110) and Pt(111) single crystal electrode. The Pt single crystal electrodes were prepared with J. Clavilier method. The electrochemical experiments were conducted in a standard three-electrode cell. Before cycle volammograms, the 0.5 mol L-1 H2SO4

【基金】 国家自然科学基金(No.20476020)
  • 【会议录名称】 第十三次全国电化学会议论文摘要集(上集)
  • 【会议名称】第十三次全国电化学会议
  • 【会议时间】2005-11
  • 【会议地点】中国广东广州
  • 【分类号】O646.54
  • 【主办单位】中国化学会电化学委员会
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