【作者】 吴宇； 李文辉； 丁瑜； 胡宗球； 王成刚；

【Author】 WU Yu, LI Wen-hui, DING Yu , HU Zong-qiu, WANG Cheng-gang(College of Chemistry, Central China Normal University, Wuhan 430079 , Hubei, China; Chemistry Department, Jingmen Technical College, Jingmen 448000, Hubei, China)

【机构】 华中师范大学化学学院；

【摘要】 以吡啶和DMF为溶剂合成了3,5-二溴水杨醛水杨酰腙的Zn(Ⅱ)、Cu(Ⅱ)、Ni(Ⅱ)配合物,并培养出锌配合物晶体。通过测定配体和配合物的红外光谱、元素分析及锌配合物晶体,确定为六配位化合物,其中溶剂分子参与了配位。对锌配合物晶体的结构特征进行了解析。更多还原

【Abstract】 The complexes of copper, zinc , nickel with 3,5-dibromosalicylaldehyde salicylhydrazone were synthesized in DMF and pyridine . The crystal of zinc complex with 3,5-dibromosalicylaldehyde salicylhydrazone was obtained . Their six-coordinated forms which included solvent molecules were confirmed by characterizing them with elemental analysis, IR and X-ray diffraction . The crystal structure of zinc complex was analyzed.更多还原