【作者】 黄应平； 刘德富； 罗光富； 张德丽； 马万红； 赵进才；

【Author】 Huang Yingping Liu defu Luo Guangfu Zhang Deli Ma Wanhong Zhao jincai Hubei Provincial Key Laboratory of Preventing & Mitigating Disasters China Three Gorges University, Yi Chang 443002, China; Laboratory of Photochemistry, Center for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China

【机构】 三峡大学湖北省防灾减灾重点实验室； 中国科学院化学研究所分子科学中心；

【摘要】 以铁磺基苯基卟啉(FeTPPS4)与阴离子交换树脂(Amberlite IR-120B)负载的固定物(FeTPPS4-resin,简称FePR)为催化剂,以H2O2为氧化剂,在可见光照射下(λ>450nm),研究了对目标有毒有机染料酸性桃红(SRB)和有毒小分子有机污染物2,4-二氯苯酚(DCP)的光催化氧化降解作用和方法。可见光能有效的加速催化降解反应速率。基于实验结果,拟定光催化反应体系主要涉及羟基自由基历程。更多还原

【Abstract】 An efficient method has been developed to degrade toxic and non-biodegradable organic pollutants such as Sulforhodamine B (SRB) and 2,4-dichlorophenol (DCP). It is based on the photocatalytic power of Iron tetrasulfophenylporphyrin supported on a commercial anionic ion-exchange resin (Amberlite IRA 900) (FePR) to activate an oxidant H2O2 in aqueous media. Visible light irradiation (λ>450nm) significantly accelerates the degradation process. On the basis of the experiment results, the photocatalytic degradation pathways mainly involve the formation and reaction of OH radicals.更多还原