【作者】 綦仲明； 祝心德； 黎红梅； 朱立红；

【Author】 Qi Zhong-ming Zhu Xin-de Li Hong-mei Zhu li-hong (Department of Chemistry,Huanggang Normal Col!ege,Huangzhou,Hubei, 438000)(Department of Chemistry,Hua Zhong Normal University,Wuhan,Hubei ,430079)

【机构】 黄冈师范学院化学系； 华中师范大学化学系；

【摘要】 用微型实验方法合成了硫代磷酰肼缩邻香草醛席夫碱及其镍(Ⅱ)配合物.测定了镍(Ⅱ)配合物的晶体结构。该晶体属单斜品系,P2(1)/n空间群,晶胞参数:a=1.4805 b=0.7995c=1.5176nm β=117.9°V=1.5791nm2 Z=2 F(000)=720 R1=0.0425.金属镍与两个酚氧原子和两个亚胺氮原子配位,形成了平面正方形结构。更多还原

【Abstract】 The schiff base of o,o-diethyl-thonophosphoryl-hydrazine with o-vanillin (HVP) has been synthesized and the complex Ni (VP) 2has also been synthesized by Microscale Chemical Experiment. The crystal structure of Ni(VP)2 has been determined by X-ray crystallographic techniques. The following results were obtained. It crystallizes in the monoclinic space group P21/n.a= 1.4805 6=0.7995 c=1.5176nm β=117.9° V=1.5791nm3 Z=2 F(000)=720 R,=0.0425.The metal ion is tetra coordinated, bound to two nitrogen atoms from imine and two oxygen atoms from hydroxybenzene to form a parallelogram.更多还原