【作者】 端木传嵩； 陈彰评； 余雪松；

【Author】 DuanMu Chuan-song Chen Zhang-ping Yu Xue-song(College of Chemistry and Molecular Sciences Wuhan University Wuhan Hubei 430072 . China)

【机构】 武汉大学化学与分子科学学院；

【摘要】 为合成有机导体,高产率合成了一系列5,15-二噻吩基卟啉、5,15-二联噻吩基卟啉和它们的金属配合物。用FeCl3为氧化剂,化学氧化聚合5,15-二联噻吩基卟啉及其金属配合物,成功得到了含有卟啉-噻吩环的线形共聚物。其结构用元素分析和红外光谱证实,其中聚5,15-二联噻吩基卟啉的电导率达到10-6S/cm。但5,15-二噻吩基卟啉及其金属配合物不能在类似的条件下聚合,但可在金盘电极上通过电化学氧化聚合的方法得到其线型共聚物。更多还原

【Abstract】 A series of monomers of 5,15-dithienyl porphyrin, 5,15-di-bithienyl porpyrin and their metal complexes were synthesized in high yields. 5,15-Di-bithienyl porphyrin and its metal complexes were polymerized by chemical oxidation using FeCl3 as oxidant (>90%) for making organic conductor and the linear porphyrin-thiophene copolymers were obtained. The structures of the copolymers were identified by elemental analysis and IR spectra. The conductivity of poly 5,15-di-bithienyl porphyrin was measured to reach over 10-6 S/cm. 5,15- dithienyl porphyrins and its metal complexes could not be polymerized under the similar conditions, but could be polymerized by electrochemical oxidation on the gold-plate electrode.更多还原