【作者】 马淑兰； 孙翠萍； 刘迎春； 赵明新； 朱文祥； 张永安；

【Author】 Ma Shu-Ian Sun Cui-ping Liu Ying-chun Zhao Ming-xin Zhu Wen-xiang Zhang Yong-an(Departement of chemistry, Beijing Normal University, Beijing, 100875)

【机构】 北京师范大学化学系；

【摘要】 合成了未见文献报道的硝化杯-冠4杯冠化合物1。用X射线单晶衍射仪测定了它的晶体结构。化合物1分子式为2C42H48N2O10·2CH3 CN·CH2 Cl2, 晶体属单斜晶系, 空间群P 21/c,晶胞参数a=19.2038(14)A,b=19.9470(15)A,C=23.2452(17)A,β=91.994(2)°,V=8898.9A3,Z=4,F(000)=7016,Dc=1.2297mg/m3。更多还原

【Abstract】 A new nitrated calixcrown (1) has been synthesized. The crystal structure was determined by X-ray diffraction method. The molecular formula of 1 is 2C42H48N2O10·2CH3 CN ·CH2C12. It belongs to monoclinic crystal system, space group P21/c, with a=19.2038(14)A,b=19.9470(15) A, c = 23.2452(17) A,β=91.994(2)°, V=8898.9 A3,Z=4,F(000) = 7016,Dc=1.2297mg/m3.更多还原