节点文献
C60-天门冬酰氨的合成及其性能初探
SYNTHESES OF FULLERENE-ASPARAGINE AND FUNDAMENTAL RESEARCH OF ITS PROPERTY
【Author】 GUAN Wenchao SHEN Chunying(Department of Chemistry, Huazhong University of Science and Technology Wuhan 430074)
【机构】 华中科技大学化学系；
【摘要】 本文报道了由多聚甲醛和L-天门冬酰氨通过脱羧基反应生成的亚胺叶立德与C60的反应,产物通过FTIR、UV-vis光谱鉴定为C60衍生物。四球机试验表明加了C60天门冬酰氨后,可有效提高润滑添加剂OPZ的抗磨性能。
【Abstract】 The reaction of C60 with azomethine Ylides generated directly from paraformaldehyde and L-Asparagine through a deearhoxylation route is reported. The product was identified to he a fullerene derivative by FTIR and UV-Vis. Four-Ball tests show that the antiwear property of the luhrifant additive OPZ can he increased effectively by mixing with fullerene-A sparagine. This compound is also expected to have some special biological activity.
【基金】 国家自然科学基金,批准号:29674010。
- 【会议录名称】 2000年材料科学与工程新进展（下）——2000年中国材料研讨会论文集
- 【会议名称】2000年中国材料研讨会
- 【会议时间】2000
- 【分类号】O623.6
- 【主办单位】中国材料研究学会