【作者】 荔建锋； 李重河； 王世华； 陈念贻；

【Author】 Li Jianfeng Li Chonghe Wang Shihua Chen Nianyi (Shanghai Institute of Metallurgy,CAS,Shanghai,200050) *(Beijing Normal University,Beijing,100081)

【机构】 中国科学院上海冶金研究所； 北京师范大学；

【摘要】 本文用原子半径和元素电负性作为基本判别参数,203个可信的Me-Me′-X三元卤化合物的形成情况作为研究对象,利用遗传算法对其进行了非线性判别分析,总结了Me- Me′-X系三元化合物的形成规律,提出了形式简单的判别函数。并用差热分析和粉末X射线法测定了五个未知化合物的相图,证明了判别函数的正确性。更多还原

【Abstract】 A genetic algorithm (GA) is used to take a non-linear discriminant analysis of 203 Me-Me′-X halides samples with the radii of the irons and the electronegativits of the elements as the basic discrnant parameters.The regularity of the formation of these samples has been investigated and a discriminant function also has been obtained.The formation of complex iodides in M-Eu-I systems (where.M represents Li.Na.K.Rb or Cs) is predicted by this discriminant function.The predicted results are completely in agreement with the experimental facts.更多还原