【作者】 徐红； 孔颖； 刘雷； 李晋平； 王建国； 董晋湘；

【Author】 XU Hong, KONG Ying , LIU Lei, LI Jin-ping, WANG Jian-guo, DONG Jin-xiang ( Research Institute of Special Chemicals , Taiyuan University of Technology, Taiyuan 030024, China; State Key Laboratory of Coal Conversion , Chinese Academy of Sciences , Taiyuan 030001. China)

【机构】 太原理工大学精细化工研究所； 中国科学院煤转化国家重点实验室；

【摘要】 研究了吡咯烷与甲哌嗡复合有机近非水体系中笼形类沸石材料的合成规律。结果表明,甲哌嗡具有模板剂的效应．能够在吡咯烷与甲哌嗡复合的有机近非水体系中合成MTN笼形材料。采用XRD、SEM、TG-DTA方法对合成样品的特性进行了表征。数据表明,本研究体系中形成的MTN晶体尺寸达到130μm。更多还原

【Abstract】 The synthesis of clathrate compound in a near non-aqueous system comprising pyrrolidine and mepiquat chloride was investigated. Experimental results showed that mepiquat chloride played the role of a template in the synthesis of clathrate compound MTN in the aforementioned system. The as-synthesized MTN was characterized by XRD, SEM, and TG-DTA. It is indicated that the crystal size of MIN could reach to 130 μm in this near non-aqueous system.更多还原