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高温高压水中有机质热解行为的原位观测

In-situ Visualization of Organic Matter Transformation in Water at High-temperature and High-pressure

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【作者】 陈晋阳朱宪张红郑海飞

【Author】 Chen Jinyang, Zhu Xian ( School of Environmental and Chemical Engineering, Shanghai University, Shanghai 201800) Zhang Hong (Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Graduate School of the Chinese Academy of Sciences, Guangzhou 510640) Zheng Haifei (School of the Earth and Space Sciences, Peking University, Beijing 100871, China)

【机构】 上海大学环境与化工学院中国科学院广州地球化学研究所中国科学院研究生院北京大学地球与空间学院

【摘要】 采用热液压腔装置,对高温高压水中蒽和沥青质的热解行为进行了原位观测。结果表明在较高温度和压力下,有机质蒽与水混溶,混溶后直到本实验的最高温度4 2 0℃、压力4 81 .3MPa都稳定存在。在高温高压下沥青质可以与水混溶,混溶后发生降解反应,最终变成类似石墨结构的碳物质。

【Abstract】 A new technique is developed to in-situ visualize transformation of organic matter in sub-critical and supercritical water Anthracene and asphalt were studied by this technique With increasing temperature and pressure, anthracene can dissolve in water at high temperature to form a homogenous system, and it is stable from sub-critical water to supercritical water Asphalt dissolves in water at high-temperature and high-pressure, and reacts with water to form graphite

  • 【会议录名称】 第九届全国化学工艺学术年会论文集
  • 【会议名称】第九届全国化学工艺学术年会
  • 【会议时间】2005-04
  • 【会议地点】北京昌平
  • 【分类号】O621
  • 【主办单位】石油大学重质油国家重点实验室
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