【作者】 张淑华； 钟新仙； 钟凡； 兰翠玲； 蒋毅民；

【Author】 ZHANG Shu-hua,ZHONG Xin-xian,ZHONG Fan,LAN Cui-ling,JIANG Yi-min(1. Department of Chemistry,Guangxi Normal University,Guilin 541004,China;2. Department of Chemistry,Jinggangshan Normal College,Ji’an 343009; 3. Department of Chemistry,Nation Teacher Training School of Guangxi Right River,Baise 53300,China)

【机构】 广西师范大学化学化工系； 江西井冈山师院化学系； 广西右江民族师专化学系；

【摘要】 <正> 通过等物质的量的牛磺酸、水杨醛,KOH缩合反应得到牛磺酸缩水杨醛Schiff碱（TSSB）,它与Cu（Ac）₂·4H₂O和邻菲咯啉（phen）反应,得到未见报道的配合物[Cu（TSSB）·（phen）·（H₂O）]·H₂O,晶体属三斜晶系,空间群P₁^-,其晶胞参数为:α=1.059 37（19）nm,b=1.1600（2）nm,c=2.1170（4）nm;α=103.340（4）°,β=98.937（4）°,γ=105.056（3）°,V=2.398 9（7）nm³,Z=2,Dc=1.506g/cm³,μ=1.044 mm^-1,F（000）=1128.配合物通过氢键形成二聚体,在这个二聚体中,两个Cu中心的配位原子完更多还原

【Abstract】 The new compound, [Cu(TSSB) (phen) (H2O)] · H2O (TSSB = taurine salicylic Schiff base, phen=O-phenanthroline) has been synthesized and characterized by IR,elemental analysis and X-ray diffraction. The compound crystal data: triclinic space group P1-,a = 1. 059 37 (19) nm,b = 1. 160 0(2) nm,c = 2. 117 0(4)nm;a=103. 340(4)°,β=98. 937(4)°. The compound is a dimmer. In the molecule of the complex,two Cu( Ⅱ ) were coordinated by three oxygen atoms and three nitrogen atoms while the O atoms of Ac-1 groups did not coordinate. At the same time the Cu( Ⅰ ) formed a distorted octahedron geometry. The compound is an one dimensional chain complex of infinite length connecting with hydrogen bonds besides the difference of the complexes were discussed.更多还原