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(1-y)[(Na0.96-xKxLi0.04)0.5Bi0.5]TiO3-yBa(Zr0.055Ti0.945)O3无铅压电陶瓷的压电介电特性

Dielectric and piezoelectric characteristics of lead-free(l-y) [(Na0.96-x KxLi0.04)0.5Bi0.5]TiO3-yBa(Zr0.055Ti0.945)O3 ceramics

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【作者】 盖志刚王矜奉苏文斌亓鹏杜鹃明保全郑立梅

【Author】 GAI Zhi-gang WANG Jin-feng SU Wen-bing QI Peng DU Juan MING Bao-quan ZHENG Li-mei (School of Physics and Microelectronics,State Key Laboratory of Crystal Materials,Shandong University,Jinan 250100,China)

【机构】 山东大学物理与微电子学院晶体材料国家重点实验室

【摘要】 对(1-y)[(Na0.80K0.16Li0.04)0.5Bi0.5]TiO3-yBa (Zr0.055Ti0.945)O3无铅压电陶瓷进行了系统研究,获得压电应变常数 d33高达185(pC/N)的0.94[(Na0.80K0.16Li0.04)0.5 Bi0.5]TiO3-0.06Ba(Zr0.055Ti0.945)O3压电陶瓷。还研究了该材料0.94[(Na0.96-xKxLi0.04)0.5Bi0.5]TiO3-0.06Ba(Zr0.055 Ti0.945)O3的性质随 K 含量的变化。随着 Ba(Zr0.055 Ti0.945)O3含量的增加,该陶瓷材料的介电温谱峰值向左移动,其介电峰温度缓慢降低;与此相反,随着 K 掺杂量的增加,该陶瓷材料的介电温谱峰值却向右明显移动,其介电峰温度明显升高.

【Abstract】 Lead-free piezoelectric ceramics (1-y) [(Na0.80K0.16Li0.04)0.5Bi0.5]TiO3-yBa(Zr0.055Ti0.945)O3 were systematically investigated.The 0.94 [(Na0.80K0.16Li0.040.5Bi0.5]TiO3-0.06Ba(Zr0.055Ti0.945)O3 ceramics having a piezoelectric strain constant d33 as high as 185(pC/N) was obtained.Lead-free 0.94 [(Na0.96-xKxLi0.04)0.5Bi0.5]TiO3-0.06Ba(Zr0.055Ti0.945)O3 ceramics were fabricated with the variation of K content and their dielectric and piezoelectric characteristics were also investigated.As can be seen in the results,the peak of dielectric constant in the dielectric constant curve versus temperature moved leftward with the increase of Ba(Zr0.055Ti0.945)O3 content.Accordingly,The temperature corresponding to maximum dielectric constant for the ceramics decreased slowly.However,the peak of dielectric constant in the dielectric constant curve versus temperature moved rightward with the increase of K content.Accordingly,The temperature corresponding to maximum dielectric constant for the ceramics increased slightly.

【基金】 国家自然科学基金(50072013);山东省自然科学基金(Z2003F04)。
  • 【会议录名称】 第六届中国功能材料及其应用学术会议论文集(2)
  • 【会议名称】第六届中国功能材料及其应用学术会议
  • 【会议时间】2007-11
  • 【会议地点】中国湖北武汉
  • 【分类号】TM282
  • 【主办单位】重庆仪器材料研究所、中国仪器仪表学会仪表材料分会、国家仪表功能材料工程技术研究中心
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