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复合聚合物CTNI/PMMA薄膜的制备及传输损耗的研究

Preparation and propagation losses of the composite polymer HTCU/PMMA films

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【作者】 张福军任诠张健孙香冰王彦玲杨旭东高怡杨洪亮张光辉Yuk Tak Chow许东

【Author】 Fujun Zhang1, Quan Ren1,Jian Zhang2 , Yanling Wang,Xiangbin Sun1, Xudong Yang1, Yi Gao1, Hongliang Yang1,Yuk Tak Chow3 ,Dong Xu2 1 School of Information Science and Engineering, Shandong University, Jinan 250100, China 2 State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China 3The Optoelectronics Research Centre, City University of Hong Kong, Kowloon, Hong Kong

【机构】 山东大学信息科学与工程学院山东大学晶体材料研究所国家重点实验室香港城市大学光电研究中心

【摘要】 合成了一种新型有机金属配合物:[C16H33(CH3)3N]Ni(dmit)2(简称为CTNI),通过旋涂法制备了不同质量比的复合聚合物CTNI/PMMA薄膜,分析和讨论了多种测量聚合物薄膜光传输损耗的方法,并用视频摄像技术测量了其光传输损耗。视频摄像技术具有测量装置简单、准确、实时、非接触等优点,测量结果表明,对8%wt掺杂浓度的CTNI/PMMA聚合物复合薄膜的光传输损耗为3.001dB/cm,随着CTNI在复合聚合物薄膜中浓度的增加,薄膜的光传输损耗线性增长。

【Abstract】 a novel dmit2- salt: (Hexadecyltrimethylammonium)- bis(4,5-dithiolato-1,3-dithiole-2-thione)copper, abbreviated as HTCu, is synthesized .The composite polymer films HTCU/PMMA are prepared by spin-coating method and the propagation losses of the composite polymer HTCU/PMMA films are measured by photographic technique which is simple both in construction and during the measurement. Such a configuration enables us to determine the propagation losses without considering the coupling efficiency into and out of the guide and of the laser fluctuation and it is a real-time, non-contact, accurate method. The propagation losses of HTCU/PMMA composite polymer films with five different guest concentrations are measured, and the results are consistent with the theoretical analysis. At last the method and results are discussed.

  • 【会议录名称】 第14届全国晶体生长与材料学术会议论文集
  • 【会议名称】第14届全国晶体生长与材料学术会议
  • 【会议时间】2006-11
  • 【会议地点】中国福建福州
  • 【分类号】TB383.2
  • 【主办单位】中国硅酸盐学会晶体生长与材料分会
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