【作者】 袁光辉； 薛冬峰；

【Author】 YUAN Guanghui XUE Dongfeng (State Key Laboratory of Fine Chemicals,Department of Materials Science and Chemical Engineering,School of Chemical Engineering,Dalian University of Technology,Dalian 116012)

【机构】 大连理工大学化工学院材料化工系精细化工国家重点实验室；

【摘要】 从硼酸盐晶体的结构出发,综述了硼酸盐的不同分类方法,并在此基础上详细介绍了复杂晶体化学键理论及其在硼酸盐晶体非线性光学性质上的应用。此外,介绍了键合模型及其对硼酸盐晶体结构的预测,提出了从硼酸盐的结构预测到结构分类再到非线性光学效应计算的一体化的硼酸盐晶体材料设计的新思路。更多还原

【Abstract】 On the basis of the borate structures,several different classifications are reviewed.Phillips-Van Vechten-Levine-Xue bond theory is detailed introduced with its general applications on the non-linear optical properties of borates.Furthermore,borate structures are predicted with the bonding model.A novel idea on designing new borate materials is proposed,which is based on the current classification,the P-V-L-X theory and the bonding model.更多还原