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裂片核素在岩石中的迁移研究——137Cs在花岗岩中渗透迁移及吸附动力学
Migration Studies of Fisson Product Nuclides in Rocks——the Permeability and the Kinetics of Adsorption for137Cs in Granite
【Author】 WEN Rui-yuan,CHANG Hui,WANG Xiang-yun,GAO Hong-cheng (Department of Technical Physics,Peking University,Beijing,100871)
【机构】 北京大学技术物理系;
【摘要】 用动态模型方程描述了裂片核素137Cs(实验中用134Cs模拟)随地下水流在花岗岩中的渗透迁移过程。由渗透曲线拟合求得模型参数——综合扩散-弥散系数和吸附速率常数,并在自行设计的水浴恒温槽中,进行了134Cs在花岗岩片上的吸附动力学研究。测定不同,pH值和不同温度下的吸附曲线,推算出相应条件下的吸附速率常数及不同pH值时的吸附能。
【Abstract】 Abstract The permeability of 137Cs in granite is studied with 134Cs as its simulation nuclide and the kinetic curves of adsorption are measured in a specially designed cell at different pH and temperatures.The kinetic constants and activation energy are obtained.The corresponding kinetic equation describing the migration of 137Cs is suggested. A series of the important parameters of diffusion,permeability and adsorption are determined.The calculated and experimentally observed dates are compared and discussed.
【Key words】 137Cs; kinetic constant of adsorption; activation energy of adsorption;
- 【会议录名称】 中国高放废物地质处置十年进展
- 【会议时间】2004-07-01
- 【分类号】O647.31