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硅异质结太阳电池中单晶硅表面织构的优化研究
OPTIMIZATION OF THE TEXTURIZATION ON C-SI WAFERS FOR HETEROJUNCTION SILICON SOLAR CELLS
【作者】 豆玉华; 周玉琴; 朱美芳; 宋爽; 刘丰珍; 刘金龙;
【Author】 Dou Yuhua~1,Zhou Yuqin*~1,Zhu Mei fang~1,Song Shuang~2,Liu Fengzhen~1,Liu Jinlong 1(1 Graduate University of the Chinese Academy of Sciences,P.O.Box 4588,Beijing 100049; 2 Beijing Solar Energy Institute.Beijing 100083)
【摘要】 采用新型的刻蚀剂,碳酸钠(Na2CO3)和磷酸钠(Na3PO4·12H2O)实现了晶硅表面的织构。研究了刻蚀剂浓度、温度(T)、刻蚀时间(te)和添加剂对晶硅表面织构的影响,讨论了刻蚀机理。通过优化工艺,得到低的平均表面反射率(Rav):9.70%(NaOH)、9.76%(Na2CO3)阳8.63%(Na3PO4·12H2O)。添加剂IPA在Na3PO4·12H2O或Na2CO3溶液中可明显地改善织构效果。将优化工艺应用到异质结太阳电池中,改善了电池的短路电流。
【Abstract】 Using new etchants of sodium carbonate and tribasic sodium phosphate,the effect of echant concentration,etching temperature,etching time and additiveon texturization of(100) crystalline silicon(c-Si) wafer was studied.By optimized the etching parameters,the lowest values of averaged reflectance(Rav) were obtained to be 9.70%for NaOH,9.76%for Na2CO3 and 8.63%for Na3PO4.12H2O.The mechanism of texturization by different kinds of etchant was suggested.Moreover,special emphasis was put on the role of isopropyl alcohol(IPA) for texturization.It is proved that IPA can remarkably improve the morphology of the textured surface. The optimized technique was applied to heterojunction silicon solar cells.Short current of the solar cell was ameliorated.
【Key words】 Crystalline silicon; Texturization; Alkaline; Reflectance; heterojunction solar cell;
- 【会议录名称】 第十届中国太阳能光伏会议论文集:迎接光伏发电新时代
- 【会议名称】第十届中国太阳能光伏会议
- 【会议时间】2008-09-19
- 【会议地点】中国江苏常州
- 【分类号】TM914.41
- 【主办单位】中国可再生能源学会、江苏省常州市人民政府、中国可再生能源学会太阳能光伏专委会