节点文献
Self-Assembly of two chiral supramolecules with three-dimensional porous host frameworks:(A){[FeⅡ(phen)3][FeⅢNa(C2O4)3]}n and its enantiomer
【Author】 Xiao-ming Lu Pei-zhou Li Bo Liu Xiao-jun Wang Department of Chemistry,Capital Normal University,Beijing 100037,P.R.China
【机构】 Department of Chemistry,Capital Normal University;
【摘要】 <正>Two oxlate Chiral supramoleCUleS with enantiomeric thfee-dimensional porous host frameworks: (△){[FeⅡ(phen)3][FeⅢNa(C2O4)3]}n(1),and(△){[FeⅡ(phen)3][FeⅢNa(C2O4)3]}n(2),(phen=1,10- phenanthroline),have been synthesized and their crystal structures have been determined.StruCtural analysis shOWS that they are enantiomers,and the circular dichroism(CD)spectrum measurements confirmed the enantiomeric nature.
- 【会议录名称】 中国晶体学会第四届全国会员代表大会暨学术会议学术论文摘要集
- 【会议名称】中国晶体学会第四届全国会员代表大会暨学术会议
- 【会议时间】2008-07-27
- 【会议地点】中国安徽黄山
- 【分类号】O627
- 【主办单位】中国晶体学会