【作者】 姚鹏飞； 黄富平； 边贺东； 于青；

【Author】 Peng-Fei Yao;Fu-Ping Huang;He-Dong Bian;Qing Yu;School of Chemistry & Chemical Engineering,Guangxi Normal University;

【机构】 广西师范大学化学与药学学院；

【摘要】 随着单分子磁体的发现,对多核簇的设计和合成成为近十年来的一大热门[1]。相对于多核锰簇和铁簇来说,关于多核钴簇的研究报道较少[2]。本文中,我们合成了一个Co13超分子簇和两个结构相似的Co24超分子簇,并对其磁性做了初步研究。更多还原

【Abstract】 In the past decade,much attention has been paid to the design and synthesis of polymetallic clusters,since the discovery of single-molecule magnets(SMMs).Only a limited number of highnuclear clusters are known for cobalt compared with those for manganese and iron.In this paper,we have successfully synthesized a Co13 and two similar Co24 superclusters.And the magnetic behavior of them,have been investigated briefly.更多还原