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耐高温超疏聚合物界面材料的电纺制备与性能

Bio-inspired Superhydrophobic Polymer Mat with High Thermal Stability

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【作者】 吴俊涛龚光明刘金刚孙娜赵勇江雷

【Author】 Juntao Wu 1,,Guangming Gong 1,Jingang Liu 2,Na Sun 1,Yong Zhao 1,,and Lei Jiang 1,2 1 School of Chemistry and Environment,Beihang University,100191,Beijing,China.2 Institut of Chemistry,Chinese Academy of Sciences,100190,Beijing,China.

【机构】 北京航空航天大学化学与环境学院中国科学院化学研究所

【摘要】 <正>固液两相界面的超疏浸润态是界面仿生研究中的一个重要课题,如何制备高性能的具有特殊浸润性的超疏界面材料一直是一个具有挑战性的课题。本研究通过简单的静电纺丝方法制备了新型具有微纳多级结构的含氟聚酰亚胺无纺布,此超疏水薄膜具有优异的综合性能,对水滴的粘附力高达98μN。同时,所制

【Abstract】 Superhydrophobic surface with high solid/liquid adhesion is of great fundamental and echnological importance.However,the fabrication of adhesive superhydrophobic polymer surfaces with high stability is rare,which limits the utilization of such surfaces in harsh environment.This paper illustrates a simple electrospinning way to produce fluorinated polyimide nanofibric mat with adhesive superhydrophobicity as well as high thermal stability.Water contact angle on the mat reaches as high as 158°and the adhesive force to water drop is up to 98μN.Moreover,the mat is able to stand extreme heat up to 300°C.By virtue of the facile electrospinning technique,large-area flexible mats can be easily achieved.Such electrospun fluorinated polyimide mat will possess more broad applications than ordinary organic superhydrophobic surfaces owing to its excellent stability in harsh environment.

  • 【会议录名称】 中国化学会第28届学术年会第4分会场摘要集
  • 【会议名称】中国化学会第28届学术年会
  • 【会议时间】2012-04-13
  • 【会议地点】中国四川成都
  • 【分类号】TQ340.64
  • 【主办单位】中国化学会
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