【作者】 李健； 饶小平； 商士斌； 高艳清；

【Author】 LI Jian,RAO Xiaoping,SHANG Shibin~*,GAO Yanqing (a Institute of Chemical Industry of Forest Products,CAF;National Engineering Laboratory for Biomass Chemical Utilization;Key and Open Laboratory On Forest Chemical Engineering,SFA; oKey Laboratory f Biomass Energy and Material,Nanjing 210042; b Institute of New Technology of Forestry,CAF,Beijing 100091)

【机构】 中国林业科学研究院林产化学工业研究所生物质化学利用国家工程实验室,国家林业局林产化学工程重点开放性实验室,江苏省生物质能源与材料重点实验室； 中国林业科学研究院林业新技术研究所；

【摘要】 用松香与丙烯酸通过Diels-Alder双烯加成反应得到即丙烯海松酸,丙烯海松酸再经酰氯化,酰胺化,最后与醛反应,制备了丙烯海松双酰腙衍生物,通过红外光谱、核磁共振、质谱和元素分析等对产物进行了表征,并对反应条件进行了优化,产品收率达45%～60%。更多还原

【Abstract】 Acrylpimaric acid was prepared by rosin through Diels-Alder addition reaction,then,a series of dihydrazone derivatives from acrylpimaric acid were synthesized.Their structures were characterized by IR, ~1H NMR,MS,and elemental analysis,the reaction conditions of these derivatives were optimized,and their yields are between 45%～60%.更多还原