【作者】 梅光泉； 伍金虎； 曾锦萍； 黄可龙；

【Author】 MEI Guang-Quan~(*1) WU Jin-Fu~1 ZENG Jin-Ping~1 HUANG Ke-Long~2 (1 Key Laboratory of Jiangxi University for Applied Chemistry and Chemical Biology, Yichun University,Yichun 336000 China 2 College of Chemistry and Chemical Engineering,Central South University,Changsha 410083 China)

【机构】 宜春学院江西省高校应用化学与化学生物学重点实验室； 中南大学化学化工学院；

【摘要】 <正>近年来,蒽系荧光受体已经成为研究热点之一,但合成含烯醇的蒽衍生物则很少见报道。前文作者合成并研究了优良蒽系荧光受体9,10-蒽-3,3’-双（1,3-戊二烯-2,4-二醇）的性质,本文利用其作为桥基配体,用双倍量的Cu²⁺离子和二苯甲酰甲烷与之进行组装反应,得到了对应的双核铜（II）四氧杂环更多还原

【Abstract】 A novel 3,3’-（anthracene-9,10-diyl）dipentane-2,4-dione-bridged di-copper（Ⅱ） complex, [Cu₂(C₂₄H₂₀O₄)(C₁₅H₁₁O₂)₂](C₁₅H₁₁O₂ = 1,3-diphenylpropane-1,3-dione anion;C₂₄H₂₀O₄ = 3,3’-（anthracene-9,10-diyl）dipentane-2,4-dione dianion),was synthesized and characterized by the element analysis,conductivity,infrared spectra,electronic spectra and ESI-MS.Thermogravimetry（TG） and differential scanning calorimetry（DSC） for compound in an atmosphere of N₂ was performed.It exhibits one intense fluorescent emission band at 431 nm.The solid EPR spectra at the X- band frequencies present the signals corresponding to the dinuclear entity at room temperature,and its electronic structures have been qualitatively investigated.Its parameters have been obtained（g= 2.1238）.更多还原