【作者】 杜丽婷； 孙晶； 颜朝国；

【Author】 SUN Jing DU Li-Ting YAN Chao-Guo~* (College of Chemistry & Chemical Engineering,Yangzhou University,Yangzhou 225002)

【机构】 扬州大学化学化工学院；

【摘要】 <正>杯芳烃是当前化学研究的明星分子,关于杯芳烃及其衍生物的合成、功能化修饰,配位化学,超分子化学及其它应用等方面的研究取得了许多重要的研究进展。我们以对叔丁基杯[4]芳烃为骨架,更多还原

【Abstract】 Terpyridine metal complexes,not only have special structures,but also possess multiple properties such as electron transfer,energy transfer,irradiancy,electricity,magnetism and mechanical movement.The fusion of the terpyridine and calixarenes into a unique entity will give rise to new discovery in coordination chemistry and supramolecular chemistry.In this work we synthesized several calixarene based terpyridines and studied the preparation of polynuclear metallic complexes and their spectroscopic properties.p-t-Butylcalixarene was alkylated withω-chloroalkoxyphenylterpyridines in alkaline condition to give 1,3-alternate terpyridine subunits on calixarenes.The coordination properties of the alixarene terpyridines for transition metal ions were studied with UV-vis and fluorescent spectroscopy.更多还原