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La2O3掺杂对ZnNb2O6微波介质陶瓷微观缺陷和介电常数的影响
The influence of doping of La2O3 for the microdefects and dielectric constant of ZnNb2O6
【作者】 唐宇; 陈松; 韩艳玲; 王选理; 黄宇阳; 邓文;
【Author】 Tang Yu,Chen Song,Han Yanling,Wang Xuanli,Huang Yuyang,Deng Wen College of Physics Science and Technology,Guangxi University,Nanning 530004,China
【机构】 广西大学物理科学与工程技术学院;
【摘要】 通过测量不同La2O3含量的ZnLa2xNb2(1-x)O(6-2x)微波介质陶瓷的介电常数、符合正电子湮没辐射多普勒展宽谱和寿命谱,获取了该陶瓷的介电常数和微观缺陷的信息。结果表明:当La2O3含量较低(x<0.20)时,随着La2O3含量的增加,样品的正电子平均寿命τm和缺陷浓度减小,样品的致密度、商谱谱峰和相对介电常数εr升高。当x=0.20时,陶瓷样品的正电子平均寿命τm和缺陷浓度的最小,样品的致密度、商谱谱峰和相对介电常数εr最高。当x>0.20时,样品的正电子平均寿命τm和缺陷浓度升高,样品的致密度、商谱谱峰和相对介电常数εr降低。
【Abstract】 The dielectric constant and micro-defect information of the ZnLa2xNb2(1-x)O(6-2x) microwave dielectric ceramics with different La2O3 content can be obtained by measuring the dielectric constant,positron lifetime and coincidence Doppler broadening spectra.The experiment results show that for ZnLa2xNb2(1-x)O(6-2x) dielectric ceramics with low La2O3 content(x<0.20),with the increase of La2O3 content,the mean positron lifetimeτm and the concentration of defects decrease,while the density,the peak of the ration curve and the dielectric constant increase.The mean positron lifetimeτm and the concentration of defects reach minimum values,while the density,the peak of the ration curve and the dielectric constant reach maximum values at x=0.20.For x<0.20 sample,the mean positron lifetimeτm and the concentration of defects increase,while the density,the peak of the ration curve and the dielectric constant decrease.
【Key words】 La2O3; ZnNb2O6Microwave dielectric ceramics; dielectric constant; micro-defects;
- 【会议录名称】 第十届全国正电子湮没谱学会议论文集
- 【会议名称】第十届全国正电子湮没谱学会议
- 【会议时间】2009-11-01
- 【会议地点】中国广西南宁
- 【分类号】TQ174.12
- 【主办单位】中国科学院核分析技术重点实验室、广西大学物理科学与工程技术学院