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二氧化氯对油田回注水中细菌的杀灭效果

Sterilization effect of chlorine dioxide for bacteria in oil-field reinjection water

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【作者】 吴明松张玉玲黄君礼田禹

【Author】 Mingsong WU1, Yuling ZHANG2, Junli HUANG1, Yu TIAN1 1School of Municipal and Environmental Engineering Harbin Institute of Technology Harbin, Heilongjiang 150090, China 2. College of Environmental Science and Engineering North China Electric Power University, Baoding 071003, China

【机构】 哈尔滨工业大学市政环境工程学院城市水资源与水环境国家重点实验室华北电力大学环境科学与工程学院

【摘要】 油田回注水中的硫酸盐还原菌、腐生菌和铁细菌会造成严重的腐蚀和堵塞问题。本研究对不同条件下二氧化氯杀灭这三类细菌的效果进行了考察,结果表明,应用二氧化氯对油田回注水杀菌是非常合适的。当投量为3.0mg/L时即可满足国家标准,当投量增加至5mg/L时,杀灭率可达100%。延长反应时间可以提高杀菌率。仅反应10min即可使出水达标。温度和pH对杀灭率影响不大。60℃为和pH7~9范围内杀菌效果最好。本研究的结果对二氧化氯在油田杀菌领域的应用提供了必要参数,具有重要的应用价值。

【Abstract】 Corrosion and plugging caused by sulfate reducting bacteria, total growth bacteria and iron bacteria in the reinjection water is very severe. The sterilization efficiencies of chlorine dioxide on the three kinds of bacteria above were studied in varies conditions. The results prove that ClO2 is suitable to apply in the oil rejection water sterilizing. When the dosage was 3.0 mg/L, the bacteria remains can meet the standards, then raise the dosage up to 5.0mg/L, the sterilization can reach or very close to 100%. Higher sterilization rates can be obtained at longer reaction time. The residue of bacterial can reach the standards just at 10 min. The influence of temperature and pH value was slightly, the best sterilization rate can be gotten at 60oC, and reach to 90% when the pH is within 7~9. Necessary index is provided in the study , which is of great application value.

  • 【会议录名称】 二氧化氯研究与应用——2011二氧化氯与水处理技术研讨会论文集
  • 【会议名称】二氧化氯研究与应用——2011二氧化氯与水处理技术研讨会
  • 【会议时间】2011-05-30
  • 【会议地点】中国上海
  • 【分类号】TE45
  • 【主办单位】全国化工标准物质委员会二氧化氯专业委员会、中国二氧化氯学会、中国水处理二氧化氯专业网、上海荷瑞会展
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