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一种新型铽(Ⅲ)三元配合物的制备与发光性能
Synthesis and photoluminescent property of a novel terbium (Ⅲ) complex
【Author】 L Zhi-jun,WEI Chang-ping,REN Xiao-ming,JIA Kun,YU Min-na (School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, China)
【机构】 长春理工大学化学与环境工程学院;
【摘要】 合成了一种新型的铽三元配合物Tb(acac)3IP。对配合物进行了元素分析、红外光谱、紫外吸收光谱、激发与发射光谱分析。结果表明,配合物具有较好的发光性质。配合物中的有机配体acac和IP能够有效的把吸收的能量传递给中心Tb3+离子,强烈敏化Tb3+发光,是一种高效的绿色发光材料。
【Abstract】 A simple route has been used to synthesize a novel terbium(Ⅲ)ternary complex. The as-synthesized products show better photoluminescence properties which was characterized by elemental analysis, UV-Vis spectrum, IR spectra, fluorescent spectrum. Acac and IP as organic ligands play a significant effect in sensitization of Tb3+, which could transfer effectually the absorbed energy to the central ion Tb3+.It was proved that the products were efficient green-transmitted materials.
【Key words】 synthesized; Tb(acac)3IP; terbium; ternary complex; rare earths;
- 【会议录名称】 2009中国功能材料科技与产业高层论坛论文集
- 【会议名称】2009中国功能材料科技与产业高层论坛
- 【会议时间】2009-11-07
- 【会议地点】中国江苏镇江
- 【分类号】O641.4
- 【主办单位】中国仪表功能材料学会、江苏大学、《功能材料》期刊、《功能材料信息》期刊