节点文献
直接甲醇燃料电池用离子液体复合膜的制备及性能研究
Preparation and characterization of ionic liquid based composite membranes for DMFC
【Author】 Miao Rui-ying,Fang Yong,Tang Ling,Li Jian-ling,Wang Xin-dong~* (Department of Physical Chemistry,School of Metallurgical and Ecological Engineering,University of Science and Technology Beijing,30 College Road,Beijing 100083,China)
【机构】 北京科技大学冶金与生态工程学院理化系;
【摘要】 本文制备了直接甲醇燃料电池用的两种离子液体([α-MPyH][Tfa]和[EMIm][BF4])复合膜,并对二者的微观形貌以及电化学特征予以表征。阻抗测试结果表明,[EMIm][BF4]复合膜的电导率高于[α-MPyH][Tfa]复合膜,计时电流法对二者阻醇性能研究结果表明,[EMIm][BF4]复合膜的阻醇性能也好于[α-MPyH][Tfa]复合膜。
【Abstract】 Two kinds of ionic liquid([α-MPyH][Tfa]and[EMIm][BF4]) based composite membranes for DMFC were prepared in this paper.Their morphology and their electrochemical properties were characterized,as well. Impedance spectroscopy test shows conductivity of[EMIm][BF4]based composite membrane is higher than that of the[α-MPyH][Tfa]based composite membrane.Similarly,the methanol-resistance of the[EMIm][BF4]based composite membrane is better than that of the[α-MPyH][Tfa]based composite membrane.
【Key words】 direct methanol fuel cell(DMFC); ionic liquid; membranes; methanol-resistance;
- 【会议录名称】 第二十八届全国化学与物理电源学术年会论文集
- 【会议名称】第二十八届全国化学与物理电源学术年会
- 【会议时间】2009-11-19
- 【会议地点】中国广东广州
- 【分类号】TM911.4
- 【主办单位】中国电子学会化学与物理电源技术分会、中国电工技术学会氢能发电装置专业委员会、中国电工技术学会电池专业委员会、中国化学与物理电源行业协会