【作者】 高福磊； 姬月萍； 陈斌； 汪营磊； 刘卫孝； 丁峰； 兰英；

【Author】 GAO Fulei;JI Yueping;CHEN Bin;WANG Yinglei;LIU Weixiao;DING Feng;LAN Ying;Xi’an Modern Chemistry Research Institute;

【机构】 西安近代化学研究所；

【摘要】 以吉纳和叠氮化钠为原料,在复合溶媒中反应得到1,5-二叠氮基-3-硝基氮杂戊烷(DIANP),收率达90%以上。研究了料比、反应温度、反应时间等反应条件对产物收率和纯度的影响,确定最佳反应条件为:采用复合溶媒,吉纳和叠氮化钠的投料比为1:0.65,反应时间为6h,反应温度在90~95℃,该法操作简单、产率高,产品后处理容易。更多还原

【Abstract】 In tnis paper, 1,5-Diazido-3-nitrazapentane(DIANP)was synthesized from DINA and sodium azide in mixed solvents and the yield of DIANP is about 90%. The effects of reactant ration, reaction temperature and reaction time on the yield and purity were investigated. And the optimum reaction condition were obtained as follws: the mass ration of DINA to sodium azide was 1:0.65, reaction time was 6 h, reaction temperature was 90~95℃. This method was simple in operation and after-treatment with high yield.更多还原