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冷冻-力化学改性胶粉制备WRP/SBR共混硫化胶研究

Study on preparation of WRP/SBR blended vulcanizate by WRP freezen-force chemistry

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【作者】 鲁萍孟彩云唐小强严长浩吴德峰张明

【Author】 LU Ping~(1,2),MENG Caiyun~1,TANG Xiaoqiang~1,YAN Changhao~(1,2),WU Dengfeng~(1,2),ZHANG Ming~(1,2*) (1.College of Chemistry and Chemical Engineering,Yangzhou Univ. Yangzhou,225002,China) (2.Jiangsu Key Laboratory of Environmental Material and Environmental Engineering.Yangzhou,225002,China)

【机构】 扬州大学化学化工学院江苏省环境材料与环境工程重点实验室

【摘要】 本文利用冷冻-力化学方法对60目废胶粉进行改性,并制备了废胶粉(WRP)/丁苯橡胶(SBR)共混硫化胶,同时研究了冷冻-力化学对WRP/SBR共混硫化胶性能的影响。结果表明,当WRP/SBR的质量比40/60、WRP经过-20℃的冷冻处理后再用开炼机薄通,提高了WRP与SBR的相容性,相应共混弹性体的力学性能最佳。扫描电镜结果显示,WRP的粒子与SBR基体界面形态改善,两相间粘合力得到增强。经过冷冻-力化学处理的60目胶粉制成的WRP/SBR硫化胶的力学性能优于使用80目、100目未处理普通胶粉所制备的WRP/SBR硫化胶的力学性能。

【Abstract】 In this paper,60 mesh waste rubber powder(WRP)was modified by the method of frozen-force chemistry and waste rubber powder(WRP)/styrene-butadiene rubber(SBR)was prepared.The influence of the frozen-force chemiscal method and WRP/SBR was studied.The results showed when the ratio of WRP/SBR was 40/60 and the WRP was frozen-20℃and was sheared by the open two-roll mixing mill,the consistent performance WRP /SBR was improved and the physical and mechanical properties of it was the best.The SEM results showed that the interface morphology of WRP and SBR was improved and the two phase adhesion was enhanced.The mechanical properties of 60 mesh WRP(frozen -20℃)/SBR.was superior to the mechanical properties of 80 or 100 mesh WRP/SBR.

【基金】 2006年度江苏省高校自然科学重大基础研究项目(06KJA15011)
  • 【会议录名称】 废旧塑料橡胶资源化利用技术与新装备开发交流研讨会论文集
  • 【会议名称】废旧塑料橡胶资源化利用技术与新装备开发交流研讨会
  • 【会议时间】2009-06-15
  • 【会议地点】中国北京
  • 【分类号】TQ333
  • 【主办单位】中国资源综合利用协会(China Association of Resource Comprehensive Utilization)
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