【作者】 张衍； 刘育建； 王井岗；

【Author】 Zhang Yan,Liu Yujian,Wang Jinggang (School of Materials Science and Engineering,East China University of Science and Technology,Shanghai 200237)

【机构】 华东理工大学材料科学与工程学院；

【摘要】 研究了烯丙基苯醚和烯丙基苯酚合成方法并表征了其性能。讨论了烯丙基苯醚的合成及其转位成烯丙基苯酚反应的部分影响因素。结果表明,以丙酮为溶剂,NaOH为碱,烯丙基苯醚的纯度和产率均较高,分别为84.9%和89.4%;200℃下6h,98.2%的烯丙基苯醚转位成烯丙基苯酚。红外光谱,质谱,核磁共振氢谱对产物表征证明,合成物为目的产物。更多还原

【Abstract】 As the simplest modifiers for bismaleimide(BMI),allyl phenyl ether and 2-allyl phenol are synthesized and characterized.With very low viscosity,they can be used in RTM.The result shows acetone as solvent and NaOH as alkali,the purity of allyl phenyl ether can be reached to 84.9%with 89.4%yield;After 6,98.2%allyl phenyl ether is converted to 2-allyl phenol in 200℃.The structures of compounds are analyzed by FT-IR,MS and ~1H-NMR.更多还原