【作者】 张素华；

【导师】 石尧成；

【作者基本信息】 扬州大学 ， 有机化学， 2007， 硕士

【摘要】 烯胺酮和卟啉化合物具有丰富的反应化学和结构化学,是有机合成中的重要中间体,而且在生物、催化和材料科学领域中具有重要应用价值,一直以来是人们研究的热点。为此,我们开展了对烯胺酮和卟啉化合物的合成与性质研究,并研究了烯胺酮和卟啉与二价金属的配位,取得了一系列有意义的创新性成果。1.本论文共合成了十六个普通烯胺酮和三个卟啉烯胺酮以及十二个烯胺酮二价金属配合物,共三十一个化合物。除用元素分析、核磁共振、红外光谱和紫外光谱表征其结构外,还用单晶X射线衍射方法测定了九个代表物的晶体结构。2.系统研究了β-二酮与芳香伯胺和脂肪族二胺的反应,合成了一系列Z-s-Z型烯胺酮化合物。研究了烯胺酮与二价铜离子的配位反应,合成了一系列新的配合物。配合物[C5H5FeC5H4COCH=C(2-NCH2C5H4N)CH3]Cu(OAc)的结构经单晶X-射线衍射确定,证明其中烯胺酮是三齿负一价配体。3.初步研究了β-二酮与氨基卟啉的反应,合成出三种新的烯胺酮化合物。4.初步研究了卟啉烯胺酮与二价金属离子的配位反应,合成了一系列新的配合物。更多还原

【Abstract】 Enaminone and porphyrin compounds have various reactivities and plentiful structural chemistry, so these compounds are important intermediates of organic synthesis and have their important applications in the fields of biology, catalysis and materials science, which have been receiving considerable attentions for long. For these,we initiated the studies on syntheses and properties of these compounds and their metal complexes, making a series of significant and creative developments.1. Sixteen normal enaminones, three porphyrin enaminones and twelve enaminone metal complexes, thirty-one compounds in all were synthesized and fully characterized by elemental analyses, 1HNMR, IR and UV sepctroscopies as well as by the single crystal structures of nine typical compounds determined by X-Ray diffraction methods.2. The reactions ofβ-diketone and primary alkylamines, aliphatic diamines were systematically studied and a series of Z-s-Z enaminones synthesized, the coordination reactions of synthesized enaminones with bivalent copper ion were researched in detail with a series of complexes synthesized. The structure of complex C5H5FeC5H4COCH=C(2-NCH2C5H4N)CH3Cu(OAc) was determined by the X-ray diffraction in which the enaminone is a tridentate ligand.3. The reactions ofβ-diketones and ATPP were preliminary studied and three new porphyrin-containing enaminones synthesized.4. The reactions of porphyrin enaminones with bivalent metal ions were primarily studied and a series of new metal complexes synthesized.更多还原