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高速轧制块体纳米晶Zn-Cu-Sr-Li合金的显微组织演变和力学性能(英文)

Microstructure evolution and mechanical properties of bulk nanocrystalline Zn-Cu-Sr-Li alloy processed by high-speed rolling

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【作者】 杨泽旭赵思聪王雷冯义成郭二军

【Author】 Ze-xu YANG;Si-cong ZHAO;Lei WANG;Yi-cheng FENG;Er-jun GUO;Key Laboratory of Advanced Manufacturing and Intelligent Technology (Ministry of Education), School of Material Science and Chemical Engineering, Harbin University of Science and Technology;Research Institute of Aero-Engine, Beihang University;

【通讯作者】 赵思聪;郭二军;

【机构】 哈尔滨理工大学材料科学与化学工程学院先进制造与智能技术教育部重点实验室北京航空航天大学航空发动机研究院

【摘要】 为满足生物医用领域对高性能合金的迫切需求,采用高速轧制技术制备了纳米晶Zn-3Cu-0.2Sr-xLi(x=0,0.2, 0.4,质量分数,%)合金。在高速轧制过程中产生了大量位错,为再结晶提供了充足的驱动力。添加Li元素能够促进相和β相的形成,这些第二相提供了丰富的异质形核位点和强的钉扎作用,在促进再结晶晶粒形核的同时抑制其长大。Li元素含量为0.4%(质量分数)的合金经高速轧制后,晶粒尺寸从181.8μm减小至50 nm。Li元素含量为0.4%(质量分数)的轧制态合金的极限抗拉强度、屈服强度和伸长率分别为433.3 MPa、389.2 MPa和15.2%,与未添加Li元素的铸态合金相比,屈服强度提高了173%,伸长率提升了591%。纳米晶强化是主要的强化机制,对轧制态Zn-3Cu-0.2Sr-0.4Li合金屈服强度的贡献率高达70.4%。

【Abstract】 Nanocrystalline Zn-3Cu-0.2Sr-xLi(x=0, 0.2, 0.4, wt.%) alloys were prepared via high-speed rolling to meet the urgent demand for high-performance alloys in the biomedical field. The high-speed rolling process generated numerous dislocations, providing sufficient driving force for recrystallization. The addition of Li promoted the formation of ε and β phases. These secondary phases provided abundant heterogeneous nucleation sites and a strong pinning effect, facilitating recrystallized grain nucleation while inhibiting its growth. The grain size of the alloy containing 0.4 wt.% Li was refined from 181.8 μm to 50 nm after rolling. The ultimate tensile strength, yield strength, and elongation of the rolled alloy containing 0.4 wt.% Li achieved 433.3 MPa, 389.2 MPa, and 15.2%, respectively. Compared to the as-cast Li-free alloy, 0.4 Li alloy demonstrated a 173% increase in yield strength and a 591% improvement in elongation. Nanocrystalline strengthening was the dominant mechanism, contributing 70.4% to the total yield strength of the rolled Zn-3Cu-0.2Sr-0.4Li alloy.

【基金】 the financial support from the National Natural Science Foundation of China (No. 51804090);Natural Science Foundation of Heilongjiang Province, China (No. YQ2023E037);Heilongjiang Provincial Key Research and Development Program, China (No. GZ20230005);China Postdoctoral Science Foundation (No. 2023MD744217);the Heilongjiang Province Postdoctoral Science Foundation, China (No. LBH-Z23299)
  • 【文献出处】 Transactions of Nonferrous Metals Society of China ,中国有色金属学报(英文版) , 编辑部邮箱 ,2026年06期
  • 【分类号】TG335;TG146.13
  • 【下载频次】81
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